Si dangling bonds at the interface of quasi-free-standing monolayer graphene (QFMLG) are known to act as scattering centers that can severely affect carrier mobility. Herein, we investigate the atomic and electronic structure of Si dangling bonds in QFMLG using low-temperature scanning tunneling microscopy/ spectroscopy (STM/STS), atomic force microscopy (AFM), and density functional theory (DFT) calculations. Two types of defects with different contrast were observed on a flat graphene terrace by STM and AFM; in particular, their STM contrast varied with the bias voltage. Moreover, these defects showed characteristic STS peaks at different energies, 1.1 and 1.4 eV. The comparison of the experimental data with the DFT calculations indicates that the defects with STS peak energies of 1.1 and 1.4 eV consist of clusters of three and four Si dangling bonds, respectively. The relevance of the present results for the optimization of graphene synthesis is discussed.
|Titolo:||Atomic and electronic structure of si dangling bonds in quasi-free-standing monolayer graphene|
|Data di pubblicazione:||2018|
|Settore Scientifico Disciplinare:||Settore FIS/03 - Fisica della Materia|
|Parole Chiave:||Atomic force microscopy; Carrier mobility; Density functional theory; Hydrogen intercalation; Quasi-free-standing monolayer graphene; Scanning tunneling microscopy; Scanning tunneling spectroscopy|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1007/s12274-017-1697-x|
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