The total angular momentum (J =1,10) S matrix elements of the Li+HF reaction have been calculated using a time independent method, and matrix transformed to the stereodirected and Gauss Legendre discrete variable representations.This paper extends to higher partial waves the study on the stereodynamics of the Li+HF reaction performed at a total angular momentum J =0. The work is focused on the orbital angular momentum (L) substates rather than on the projections K on the intermolecular axis and emphasis is given to a space-fixed rather than to a body-fixed view of the collision process. A detailed comparison of stereodirected and discrete variable representations is also made.
|Titolo:||Correlation of attack and recoil angles for the Li +HF reaction: An exact quantum mechanical study at low and high total angular momentum|
|Data di pubblicazione:||2008|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1016/j.chemphys.2008.02.037|
|Appare nelle tipologie:||1.1 Articolo in rivista|