CINECA IRIS Institutional Research Information System
IRIS è la soluzione IT che facilita la raccolta e la gestione dei dati relativi alle attività e ai prodotti della ricerca. Fornisce a ricercatori, amministratori e valutatori gli strumenti per monitorare i risultati della ricerca, aumentarne la visibilità e allocare in modo efficace le risorse disponibili.
EnglishCis-RuCl2(diphosphine)(CAMPY) complexes, chiral at the metal centre with matching or mismatching chiralities between diphosphine and CAMPY were prepared and the configuration at the metal was determined in solution by a complete set of NMR investigations; CAMPY is (R)-(-) or (S)-(+)-8-amino-5,6,7,8-tetrahydroquinoline. The complexes were used in ATH reactions of different aryl ketones with 2-propanol as hydrogen source. The effects of the chirality at the metal were studied and enantiomeric excesses up to 99% were obtained.
| Titolo: | Diastereoselectivity and catalytic activity in ruthenium complexes chiral at the metal centre | |
| Autori: | ||
| Data di pubblicazione: | 2014 | |
| Rivista: | ||
| Parole Chiave: | 8-Amino-5,6,7,8-tetrahydroquinoline; ATH; Metal chirality; Ruthenium; Biochemistry; Physical and Theoretical Chemistry; Organic Chemistry; Inorganic Chemistry; Materials Chemistry2506 Metals and Alloys | |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.jorganchem.2014.06.016 | |
| Handle: | http://hdl.handle.net/11384/69551 | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
http://hdl.handle.net/11384/69551
Copyright © 2021