Cis-RuCl2(diphosphine)(CAMPY) complexes, chiral at the metal centre with matching or mismatching chiralities between diphosphine and CAMPY were prepared and the configuration at the metal was determined in solution by a complete set of NMR investigations; CAMPY is (R)-(-) or (S)-(+)-8-amino-5,6,7,8-tetrahydroquinoline. The complexes were used in ATH reactions of different aryl ketones with 2-propanol as hydrogen source. The effects of the chirality at the metal were studied and enantiomeric excesses up to 99% were obtained.

Diastereoselectivity and catalytic activity in ruthenium complexes chiral at the metal centre

Fusè, Marco
2014

Abstract

Cis-RuCl2(diphosphine)(CAMPY) complexes, chiral at the metal centre with matching or mismatching chiralities between diphosphine and CAMPY were prepared and the configuration at the metal was determined in solution by a complete set of NMR investigations; CAMPY is (R)-(-) or (S)-(+)-8-amino-5,6,7,8-tetrahydroquinoline. The complexes were used in ATH reactions of different aryl ketones with 2-propanol as hydrogen source. The effects of the chirality at the metal were studied and enantiomeric excesses up to 99% were obtained.
2014
8-Amino-5,6,7,8-tetrahydroquinoline; ATH; Metal chirality; Ruthenium; Biochemistry; Physical and Theoretical Chemistry; Organic Chemistry; Inorganic Chemistry; Materials Chemistry2506 Metals and Alloys
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11384/69551
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