The 3d transition metal ions (TMI) substituting for the cations in the tetrahedrally coordinated zincblende II-VI semiconductors display a localized mode above the rest-strahlen when introduced in dilute concentrations. The local mode observed in the infrared exhibits a characteristic dependence on the isotopic mass of the TMI. In the wurtzite II-VIs, the local mode undergoes a splitting into two components, one polarized along the optic axis and the other normal to it. The local mode frequency shows a striking non-monotonic dependence on the number of 3d electrons of the TMI.

LOCAL MODES OF SUBSTITUTIONAL TRANSITION-METAL IONS IN II-VI SEMICONDUCTORS

LA ROCCA, Giuseppe Carlo;
1994

Abstract

The 3d transition metal ions (TMI) substituting for the cations in the tetrahedrally coordinated zincblende II-VI semiconductors display a localized mode above the rest-strahlen when introduced in dilute concentrations. The local mode observed in the infrared exhibits a characteristic dependence on the isotopic mass of the TMI. In the wurtzite II-VIs, the local mode undergoes a splitting into two components, one polarized along the optic axis and the other normal to it. The local mode frequency shows a striking non-monotonic dependence on the number of 3d electrons of the TMI.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11384/7672
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 7
  • ???jsp.display-item.citation.isi??? 7
  • OpenAlex ND
social impact