The first practical access to 4-hydroxy-6-(2-amino-2-carboxyethyl)benzothiazole and 4-hydroxy-7-(2-amino-2-carboxyethyl)benzothiazole (1b and 2b) and the corresponding 2-carboxy-derivs. 1a and 2a is reported, involving one-pot sequential Zn2+-assisted biomimetic oxidn. of -dopa and -cysteine, 5-S-cysteinyldopa or 2-S-cysteinyldopa.
Biologically inspired one-pot access routes to 4-hydroxybenzothiazole amino acids, red hair-specific markers of UV susceptibility and skin cancer risk
d'Ischia M.
2009
Abstract
The first practical access to 4-hydroxy-6-(2-amino-2-carboxyethyl)benzothiazole and 4-hydroxy-7-(2-amino-2-carboxyethyl)benzothiazole (1b and 2b) and the corresponding 2-carboxy-derivs. 1a and 2a is reported, involving one-pot sequential Zn2+-assisted biomimetic oxidn. of -dopa and -cysteine, 5-S-cysteinyldopa or 2-S-cysteinyldopa.File in questo prodotto:
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