Exposure of α-tocopherol [I; R = Me(CHMeCH2CH2CH2)3] to nitric oxide (NO) in air-satd. cyclohexane leads to a complex mixt. of products, one of which, relatively more polar, has been isolated and identified as the novel 2,3-dimethyl-4-acetyl-4-hydroxy-5-nitroso-2-cyclopentenone deriv. II [R = Me(CHMeCH2CH2CH2)3].
Nitrosation-oxidative ring contraction of alfa-tocopherol by reaction with nitric oxide under aerobic conditions
M. D'ISCHIA
1995
Abstract
Exposure of α-tocopherol [I; R = Me(CHMeCH2CH2CH2)3] to nitric oxide (NO) in air-satd. cyclohexane leads to a complex mixt. of products, one of which, relatively more polar, has been isolated and identified as the novel 2,3-dimethyl-4-acetyl-4-hydroxy-5-nitroso-2-cyclopentenone deriv. II [R = Me(CHMeCH2CH2CH2)3].File in questo prodotto:
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