5,6-Dihydroxyindole oligomers are valuable synthetic targets for the structural characterization of eumelanin biopolymers as well as for the realization of bioinspired functional materials. An ortho-alkynylaniline-based strategy allowed the first access to a trimer, the missing 5,5',5'',6,6',6''-hexaacetoxy-2,7':2',7''-triindole, and its detection as a minor intermediate en route from 5,6-dihydroxyindole to eumelanin-like polymers.

First synthetic entry to the trimer stage of 5,6-dihydroxyindole polymerization: ortho-alkynylaniline-based access to the missing 2,7':2',7''-triindole

D'ISCHIA, MARCO
2010

Abstract

5,6-Dihydroxyindole oligomers are valuable synthetic targets for the structural characterization of eumelanin biopolymers as well as for the realization of bioinspired functional materials. An ortho-alkynylaniline-based strategy allowed the first access to a trimer, the missing 5,5',5'',6,6',6''-hexaacetoxy-2,7':2',7''-triindole, and its detection as a minor intermediate en route from 5,6-dihydroxyindole to eumelanin-like polymers.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11384/84236
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