An unusual rearranged trimer, 2-(2-amino-4,5-dihydroxybenzyl)-6,7-dihydroxy-3-(5,6-dihydroxyindol-3-yl)quinoline (1a), was obtained as the acetyl deriv. (1b) by mild acid-promoted polymn. of 5,6-dihydroxyindole at pH 2. Compd. 1b proved to be a selective fluoride-sensing compd., transducing F- binding into a distinct absorption at 414 nm and a marked fluorescence enhancement at 489 nm.
A novel fluoride-sensing scaffold by a peculiar acid-promoted trimerization of 5,6-dihydroxyindole
D'ISCHIA, MARCO
2009
Abstract
An unusual rearranged trimer, 2-(2-amino-4,5-dihydroxybenzyl)-6,7-dihydroxy-3-(5,6-dihydroxyindol-3-yl)quinoline (1a), was obtained as the acetyl deriv. (1b) by mild acid-promoted polymn. of 5,6-dihydroxyindole at pH 2. Compd. 1b proved to be a selective fluoride-sensing compd., transducing F- binding into a distinct absorption at 414 nm and a marked fluorescence enhancement at 489 nm.File in questo prodotto:
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