Strong light-matter coupling gives rise to polaritons - hybrid excitations whose mixed photonic and matter character enables control over optical, electronic and chemical properties. This Feature Article reviews the main architectures supporting polariton formation, including photonic microcavities, plasmonic nanostructures, open cavities and metasurfaces, and outlines how inorganic semiconductors, organic aggregates and hybrid systems access strong and ultrastrong coupling. Key phenomena such as coherent dynamics, vibronic interactions, dark-state reservoirs and polariton-mediated energy and electron transport are discussed, together with the experimental and theoretical tools used to study them. We highlight examples where strong coupling modifies charge transport, energy flow and chemical reactivity, and we summarize emerging regimes, including intermediate and dark-strong coupling, that broaden the landscape of hybrid light-matter physics.

Strong light–matter interactions in hybrid polaritonic systems

Giovannini, Tommaso;Cappelli, Chiara;Corni, Stefano;
2026

Abstract

Strong light-matter coupling gives rise to polaritons - hybrid excitations whose mixed photonic and matter character enables control over optical, electronic and chemical properties. This Feature Article reviews the main architectures supporting polariton formation, including photonic microcavities, plasmonic nanostructures, open cavities and metasurfaces, and outlines how inorganic semiconductors, organic aggregates and hybrid systems access strong and ultrastrong coupling. Key phenomena such as coherent dynamics, vibronic interactions, dark-state reservoirs and polariton-mediated energy and electron transport are discussed, together with the experimental and theoretical tools used to study them. We highlight examples where strong coupling modifies charge transport, energy flow and chemical reactivity, and we summarize emerging regimes, including intermediate and dark-strong coupling, that broaden the landscape of hybrid light-matter physics.
2026
Settore CHEM-02/A - Chimica fisica
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   MagneticTWIST
   European Commission
   Horizon Europe Framework Programme - European Research Council - HORIZON ERC Grants
   101116253

   Long-lived coherent Rabi oscillations in molecular polaritons and their application to ultrafast all-optical switching
   CORALS
   European Commission
   Horizon Europe Framework Programme - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships
   101205787

   ManipULation of photoinduced processes bY reshaping tranSition StatEs via transient Strong coupling
   ULYSSES
   European Commission
   Horizon Europe Framework Programme - European Research Council - HORIZON ERC Grants
   101077181

   The PhotoControl project
   MUR
   PRIN 2022
   2022N8PBLM

   Photoinduced ultrafast carriers and thermal effects within metasurfaces for light-driven catalysis
   PATHWAYS
   European Commission
   Horizon Europe Framework Programme - HORIZON TMA MSCA Postdoctoral Fellowships - Global Fellowships
   101153856

   General Embedding Models for Spectroscopy (GEMS)
   GEMS
   European Commission
   H2020
   818064
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11384/170525
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